Here’s a GREAT painting guide that you could easily translate to any model! Check it out!
Here’s a guide as to how I panted up my Rebs Force.
The first thing to say is there were a few basic colours that stayed the same throughout the force; the armour, blacks, reds, metals and leather. So here’s a rundown of how those colours were achieved:
Armour: The armour was painted in the same fashion as my Deadzone terrain. Take a look HERE to see how that was acheived.
Blacks: Basecoat with Abaddon Black
Highlight of Mechanicus Standard Grey with a touch of Hawk Turquoise focussing on the top edge of the folds and raised areas
Highlight of Codex Grey with a touch of Hawk Turquoise
Fine Highlight of Fortress Grey with a touch of Hawk Turquoise
Was of Nuln oil mixed with a bit of Lahmian Medium
Reds: Over the Khorne Red base:
Layer of Mephiston Red leaving the recesses the original colour
Highlight of Evil Sun Scarlet
Highlight…
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Miniature armies, huge time sink. 
Nice, I like the use of lines on the cloak instead of the typical smooth blend shading. Definitely gives it a cooler sci fi vibe. Cool looking fun sci fi models too 🙂